A thermodynamic process is the transformation of a system from one equilibrium state to another, involving changes in conditions like temperature, pressure, and volume. Energy transfer and work can occur during these processes, as illustrated by a piston and cylinder example.
An isothermal process, derived from Greek words meaning 'equal heat', maintains a constant temperature throughout the change from initial to final state (dT=0). An example is water boiling at a constant temperature.
An adiabatic process, meaning 'impossible' for heat transfer, involves no exchange of heat between the system and surroundings (dQ=0). It's considered perfectly insulated, with energy transferred only as work. A hot water in a thermos is a good example.
An isochoric process, meaning 'same space or volume', maintains a constant volume during the change from initial to final state (dV=0). Boiling water in a closed vessel is an example, as the volume remains unchanged.
An isobaric process, meaning 'equal pressure', maintains a constant pressure throughout the change from initial to final state (dP=0). Boiling water in an open vessel occurs at constant atmospheric pressure, making it an isobaric process.
A cyclic process occurs when a system returns to its original state after a series of changes, completing a cycle. In this process, the net change in internal energy is zero (dE=0, dH=0). The Carnot cycle is a prime example.
A reversible process allows the system and surroundings to be restored to their initial state without any changes to the universe, such as the melting and refreezing of ice cream. An irreversible process, conversely, cannot be restored to its initial state, like the setting of cement, sand, and water.